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rovibronic coupling : ウィキペディア英語版
rovibronic coupling

Rovibronic coupling denotes the simultaneous interactions between rotational, vibrational, and electronic degrees of freedom in a molecule. When a rovibronic transition occurs, the rotational, vibrational, and electronic states change simultaneously, unlike in rovibrational coupling. The coupling can be observed spectroscopically and is most easily seen in the Renner-Teller effect in which a linear polyatomic molecule is in a degenerate electronic state and bending vibrations will cause a large Rovibronic coupling.
== See also ==

* Afterglow plasma
* Vibronic coupling


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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